Deflating Ex-ped Mystery

OK - I admit that I skipped all the hard science subjects at school so am not great at physics or even general science. But can someone help me with explaining this. I recently did the Larapinta trail and took along my Ex-ped Downmat. As we were getting into camp early I would be inflating my Exped in the hottest part of the day (around 2pm - about 27 degrees in the tent). Every night at around 3am (also getting towards the coldest part of the night- sub 5 degrees) I would wake up to find my Exped mat flat as a pancake - I would re.pump it and it would be fine until morning. I'm nearly 100% sure it doesn't have any leaks.
What's going on?
What's going on?